Why is the second ionization energy higher than the first. For second ionisation we have to remove electrons from a positive atom where electrons are more tightly bound due to the nucleus in an ion.
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Because positive charge binds electrons more strongly.

Why second ionization energy is higher than first. Second Ionisation Energies are always higher than the first due to two main reasons. An elements second ionization energy is the energy required to remove the outermost or least bound electron from a 1 ion of the element. The second ionization energy is higher than the first ionization energy.
You are removing the electron from a position that it slightly closer to the nucleus and therefore is subject to greater attraction to the nucleus. Whereas the first ionisation electron is removed from a neutral atom.
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